Symmetric hydrogen bond

In the context of Symmetric hydrogen bond, it becomes increasingly pertinent to address the importance and relevance of this topic. For a long time, Symmetric hydrogen bond has captured the attention of people from various disciplines, generating passionate discussions and even controversies. From its origins to the present, Symmetric hydrogen bond has made a significant impact in different sectors, influencing not only the way people think and act, but also policies, the economy and society as a whole. This is why it is crucial to fully explore all facets of Symmetric hydrogen bond, to understand its true scope and influence in today's world.
Energy profiles for different hydrogen bond types between oxygen heteroatoms. Standard hydrogen bonds are asymmetrical, with the hydrogen being associated with one heteroatom. When the pKa between the heteroatoms is equal, a symmetrical hydrogen bond forms with the hydrogen properly between two locations. At shorter distances, the barrier between the two energy minima is low enough that the hydrogen is equally bound as a low-barrier, or single-well hydrogen bond.

A symmetric hydrogen bond is a special type of hydrogen bond in which the proton is spaced exactly halfway between two identical atoms. The strength of the bond to each of those atoms is equal. It is an example of a 3-center 4-electron bond. This type of bond is much stronger than "normal" hydrogen bonds, in fact, its strength is comparable to a covalent bond. It is seen in ice at high pressure (Ice X), and also in the solid phase of many anhydrous acids such as hydrofluoric acid and formic acid at high pressure. It is also seen in the bifluoride ion −. Much has been done to explain the symmetric hydrogen bond quantum-mechanically, as it seems to violate the duet rule for the first shell: The proton is effectively surrounded by four electrons. Because of this problem, some consider it to be an ionic bond.

References

  • Steiner, Thomas (2002). "The Hydrogen Bond in the Solid State". Angewandte Chemie International Edition. 41: 48–76. doi:10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U. PMID 12491444.
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