Plutonium(III) fluoride

Today, Plutonium(III) fluoride is a topic that generates great interest and debate in society. It is a theme that has been present throughout history and that continues to evolve over time. From different perspectives and approaches, Plutonium(III) fluoride has captured the attention of experts, researchers, politicians and citizens. With the advancement of technology and communications, Plutonium(III) fluoride has become an issue of global relevance, affecting people of all ages and conditions. In this article we will explore the different facets and debates that revolve around Plutonium(III) fluoride, with the aim of understanding its impact on today's society.
Plutonium(III) fluoride
Unit cell, ball and stick model of plutonium(III) fluoride
Unit cell, ball and stick model of plutonium(III) fluoride
Names
IUPAC name
Plutonium(III) fluoride
Systematic IUPAC name
Plutonium(3+) fluoride
Other names
Plutonic fluoride

Plutonium fluoride

Plutonium trifluoride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/3FH.Pu/h3*1H;/q;;;+3/p-3 checkY
    Key: DBYIUAMLRDFZJJ-UHFFFAOYSA-K checkY
  • ...
Properties
F3Pu
Molar mass 301 g·mol−1
Appearance Violet, opaque crystals
Density 9.3 g cm−3
Melting point 1,396 °C (2,545 °F; 1,669 K)[2]
Boiling point 2,000 °C (3,630 °F; 2,270 K) (decomposes)[1]
Related compounds
Other anions
 Plutonium(III) chloride
Other cations
 Samarium(III) fluoride
Related fluoroplutoniums
 Plutonium tetrafluoride

Plutonium hexafluoride

Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa).

Plutonium(III) fluoride or plutonium trifluoride is the chemical compound composed of plutonium and fluorine with the formula PuF3. This salt forms violet crystals. Plutonium(III) fluoride has the LaF3 structure where the coordination around the plutonium atoms is complex and usually described as tri-capped trigonal prismatic.[3]

Reactions

A plutonium(III) fluoride precipitation method has been investigated as an alternative to the typical plutonium peroxide method of recovering plutonium from solution, such as that from a nuclear reprocessing plant.[4] A 1957 study by the Los Alamos National Laboratory reported a less effective recovery than the traditional method,[5] while a more recent study sponsored by the United States Office of Scientific and Technical Information found it to be one of the more effective methods.[6]

Plutonium(III) fluoride can be used for manufacture of the plutonium-gallium alloy instead of more difficult to handle metallic plutonium.

References

  1. ^ Chemistry: Periodic Table: Plutonium: compound data (plutonium (III) fluoride), WebElements, retrieved 2008-06-20[permanent dead link‍]
  2. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, p. 113, ISBN 0-8493-0594-2, retrieved 2008-06-20
  3. ^ Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN 0-19-855370-6.
  4. ^ Gupta, C. K.; Mukherjee, T. K. (1990), Hydrometallurgy in Extraction Processes, vol. 2, CRC Press, pp. 206–208, ISBN 0-8493-6805-7, OCLC 21197603, retrieved 2008-06-20
  5. ^ Winchester, R. S. (1957), Aqueous Decontamination of Plutonium from Fission Product Elements (PDF), Los Alamos, NM: Los Alamos Scientific Laboratory of the University of California (published 1958), pp. 9–10, retrieved 2008-06-20
  6. ^ Martella, L. L.; Saba, M. T.; Campbell, G. K. (1984), Laboratory-scale evaluations of alternative plutonium precipitation methods, United States Office of Scientific and Technical Information, doi:10.2172/5318991, OSTI 5318991
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