Bismuth iodate

In this article, we will delve into the fascinating world of Bismuth iodate. This topic is of great interest to a wide spectrum of people, since its impact is felt in different areas of daily life. From historical aspects to its relevance today, Bismuth iodate has been the subject of studies, debates and reflections by experts and enthusiasts alike. In the next lines, we will explore the various facets of Bismuth iodate, analyzing its importance, its implications and its possible future developments. Join us on this tour of Bismuth iodate and discover everything this exciting topic has to offer!
Bismuth iodate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.834 Edit this at Wikidata
EC Number
  • 237-233-4
  • InChI=1S/Bi.3HIO3/c;3*2-1(3)4/h;3*(H,2,3,4)/q+3;;;/p-3
    Key: FGQDLCIITXBKAR-UHFFFAOYSA-K
  • dihydrate: InChI=1S/Bi.3HIO3.2H2O.6H/c;3*2-1(3)4;;;;;;;;/h;3*(H,2,3,4);2*1H2;;;;;;/q+3;;;;;;;;;;;/p-3
    Key: ZXENQEZTERBKRJ-UHFFFAOYSA-K
  • .(=O)=O.(=O)=O.(=O)=O
  • dihydrate: .(=O)=O.(=O)=O.(=O)=O.O.O
Properties
Bi(IO3)3
Molar mass 733.69
Appearance colourless crystals (dihydrate)[1]
Density 6.096 g (anhydrous)[2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa).

Bismuth iodate is an inorganic compound with the chemical formula Bi(IO3)3. Its anhydrate can be obtained by reacting bismuth nitrate and iodic acid, dissolving the resulting precipitate in 7.8 mol/L nitric acid, and heating to volatilize and crystallize at 70 °C;[2] The dihydrate can be obtained by reacting bismuth nitrate and potassium iodate or sodium iodate. It is obtained by evaporation and crystallization in 7 mol/L nitric acid at 50 °C.[1] Its basic salt BiOIO3 is known.[3]

References

  1. ^ a b Phanon, D.; Gautier-Luneau, I. (Sep 2006). "Crystal structure of bismuth triiodate dihydrate, Bi3 · 2H2O". Zeitschrift für Kristallographie - New Crystal Structures. 221 (3): 243–244. doi:10.1524/ncrs.2006.0056. ISSN 2197-4578.
  2. ^ a b Bentria, Bachir; Benbertal, Djamal; Bagieu-Beucher, Muriel; Masse, René; Mosset, Alain (2003). "[No title found]". Journal of Chemical Crystallography. 33 (11): 867–873. doi:10.1023/A:1027409929990.
  3. ^ Huang, Hongwei; Chen, Fang; Reshak, Ali Hussain; Auluck, Sushil; Zhang, Yihe (Nov 2018). "Insight into crystal-structure dependent charge separation and photo-redox catalysis: A combined experimental and theoretical study on Bi(IO3)3 and BiOIO3". Applied Surface Science. 458: 129–138. doi:10.1016/j.apsusc.2018.07.054.